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Dortmund Data Bank
Thermophysical Data for Process Design
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Query

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DDB#	Name	CAS-RN	Formula
3	Acetonitrile	75-05-8	C₂H₃N	Overview	Details
11	Ethanol	64-17-5	C₂H₆O	Overview	Details
21	Ethyl acetate	141-78-6	C₄H₈O₂	Overview	Details
72	N,N-Dimethylformamide (DMF)	68-12-2	C₃H₇NO	Overview	Details
84	Acetic acid	64-19-7	C₂H₄O₂	Overview	Details
174	Water	7732-18-5	H₂O	Overview	Details

Search for mixtures containing this mixture as subsystem

Mixture Data

Number of available sets is shown

**Vapor-Liquid Equilibria (VLE)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	18	10	1	3	48
11	Ethanol		86	9	16	372
21	Ethyl acetate			6	40	37
72	N,N-Dimethylformamide (DMF)				4	55
84	Acetic acid					184

**Heats of Mixing (HE)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	12	3	10	4	22
11	Ethanol		12	6	5	141
21	Ethyl acetate			1	5	6
72	N,N-Dimethylformamide (DMF)				1	20
84	Acetic acid					37

**Gas Solubilities (GLE)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	1	n.a.	n.a.	n.a.	4
11	Ethanol		1	1	1	10
21	Ethyl acetate			n.a.	n.a.	7
72	N,N-Dimethylformamide (DMF)				n.a.	n.a.
84	Acetic acid					5

**Activity Coefficients at Infinite Dilution (Pure Solvents) (ACT)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	4	5	n.a.	n.a.	14
11	Ethanol		35	12	1	77
21	Ethyl acetate			7	9	46
72	N,N-Dimethylformamide (DMF)				n.a.	37
84	Acetic acid					12

**Liquid-Liquid Equilibria (Miscibility Gaps) (LLE)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	n.a.	n.a.	18
11	Ethanol		n.a.	n.a.	n.a.	n.a.
21	Ethyl acetate			n.a.	n.a.	107
72	N,N-Dimethylformamide (DMF)				n.a.	n.a.
84	Acetic acid					n.a.

**Heat Capacities of Mixtures, Excess Heat Capacities (CPE)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	9	n.a.	9
11	Ethanol		3	1	n.a.	65
21	Ethyl acetate			n.a.	n.a.	3
72	N,N-Dimethylformamide (DMF)				n.a.	29
84	Acetic acid					36

**(A)zeotropic Data (AZD)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	23	14	1	3	65
11	Ethanol		119	8	15	288
21	Ethyl acetate			4	24	65
72	N,N-Dimethylformamide (DMF)				5	38
84	Acetic acid					159

**Solid-Liquid Equilibria (SLE)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	n.a.	n.a.	18
11	Ethanol		2	n.a.	2	35
21	Ethyl acetate			n.a.	1	3
72	N,N-Dimethylformamide (DMF)				4	1
84	Acetic acid					22

**Vapor-Liquid Equilibria of Electrolyte Systems (ELE)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	n.a.	n.a.	n.a.
11	Ethanol		n.a.	n.a.	n.a.	n.a.
21	Ethyl acetate			n.a.	n.a.	n.a.
72	N,N-Dimethylformamide (DMF)				n.a.	n.a.
84	Acetic acid					2

**Densities and Volumes of Mixtures, Excess Volumes (VE)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	25	7	25	7	152
11	Ethanol		53	20	10	589
21	Ethyl acetate			4	9	30
72	N,N-Dimethylformamide (DMF)				3	149
84	Acetic acid					109

**Critical Data of Mixtures (CRI)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	n.a.	n.a.	4
11	Ethanol		1	n.a.	1	9
21	Ethyl acetate			n.a.	n.a.	1
72	N,N-Dimethylformamide (DMF)				n.a.	n.a.
84	Acetic acid					2

**Mixture Viscosities (VIS)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	11	6	25	3	49
11	Ethanol		14	25	14	373
21	Ethyl acetate			1	7	4
72	N,N-Dimethylformamide (DMF)				7	79
84	Acetic acid					78

**Mixture Surface Tensions (MSFT)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	4	n.a.	4	3	9
11	Ethanol		n.a.	n.a.	1	50
21	Ethyl acetate			n.a.	1	11
72	N,N-Dimethylformamide (DMF)				n.a.	12
84	Acetic acid					17

**Mixture Speeds of Sound (MSOS)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	1	23	5	15
11	Ethanol		1	8	3	45
21	Ethyl acetate			1	4	10
72	N,N-Dimethylformamide (DMF)				n.a.	27
84	Acetic acid					7

**Mixture Thermal Conductivities (MTCN)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	1	n.a.	n.a.	n.a.	n.a.
11	Ethanol		3	1	n.a.	61
21	Ethyl acetate			n.a.	n.a.	n.a.
72	N,N-Dimethylformamide (DMF)				n.a.	8
84	Acetic acid					4

**Mixture Dielectric Constants (MDEC)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	4	6	1	n.a.	17
11	Ethanol		4	8	n.a.	35
21	Ethyl acetate			n.a.	n.a.	n.a.
72	N,N-Dimethylformamide (DMF)				n.a.	23
84	Acetic acid					2

**Mixture P-v-T Data (MPVT)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	n.a.	n.a.	4
11	Ethanol		n.a.	5	n.a.	134
21	Ethyl acetate			n.a.	n.a.	n.a.
72	N,N-Dimethylformamide (DMF)				n.a.	n.a.
84	Acetic acid					1

**Mixture Flash Points (MFLP)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	n.a.	n.a.	1
11	Ethanol		2	n.a.	n.a.	14
21	Ethyl acetate			n.a.	n.a.	n.a.
72	N,N-Dimethylformamide (DMF)				n.a.	1
84	Acetic acid					1

**Gas Hydrate Data (GHD)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	n.a.	n.a.	n.a.
11	Ethanol		n.a.	n.a.	n.a.	1
21	Ethyl acetate			n.a.	n.a.	n.a.
72	N,N-Dimethylformamide (DMF)				n.a.	n.a.
84	Acetic acid					n.a.

**Electrical Conductivities (ECND)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	1	n.a.	n.a.	n.a.	3
11	Ethanol		n.a.	n.a.	n.a.	9
21	Ethyl acetate			n.a.	n.a.	n.a.
72	N,N-Dimethylformamide (DMF)				n.a.	n.a.
84	Acetic acid					20

**Diffusion Coefficients (DIF)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	n.a.	n.a.	n.a.	n.a.	2
11	Ethanol		n.a.	n.a.	2	48
21	Ethyl acetate			n.a.	n.a.	1
72	N,N-Dimethylformamide (DMF)				n.a.	4
84	Acetic acid					3

**Further Thermodynamic Properties (X)**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	3	n.a.	1	n.a.	9
11	Ethanol		2	4	n.a.	122
21	Ethyl acetate			3	1	14
72	N,N-Dimethylformamide (DMF)				n.a.	62
84	Acetic acid					61

**Total**
DDB#	Name	11	21	72	84	174	Water
3	Acetonitrile	107	52	100	28	463
11	Ethanol		338	108	71	2478
21	Ethyl acetate			27	101	345
72	N,N-Dimethylformamide (DMF)				24	545
84	Acetic acid					762

Dortmund Data Bank Version: February 2024

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